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to zero, i.e. a 2D wave function. As the width increased, increased steadily towards unity, i.e. the 3D (spherical or bulk-like) exciton. This point that C generally lies in the limits 0 < C < 1 will be reinforced further by the use of several different example systems in the following discussions. For this reason, discussion of the symmetry of the wave function will use C and interchangeably. Figure 6.6 illustrates the variational technique in the case of the infinite well of width lw=100 A. It can be seen that there is just one minimum in the exciton energy in the two-dimensional Y-B space. This is almost always the case. However, there is an exception to this rule [131]. In double quantum well systems where the one-particle electron wave function has a significant component in each of the wells, there exists two local energy minima within A-B space. This implies that there are two possible exciton states which can be formed from the same one-particle wave functions. The two states can be thought of as originating from the localised hole binding separately with both of the 'lobes' of the electron wave function.

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Figure 6.7 The uncorrelated probability p(a) of finding the electron and hole separated by a distance a in the infinite quantum well, shown for different well widths

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The behavior is as described so far The author will be required to write custom code that decides which kind of shape to create when an element of the domain class is created Elements of each domain class will cause the same kind of shape to be created By the rst rule, A1 elements will be presented by S1 shapes, and A2 elements will be presented by S2 shapes However, any mappings between decorators and/or compartments speci ed in the mapping between A1 and S1 that are not remapped in the mapping between A2 and S2 will be used when using an S2 shape to represent an A2 element

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It is worthwhile just looking at the form of the function p(a), which plays a significant role in the theoretical analysis. As mentioned at the point of its introduction, p(a) represents the uncorrelated (i.e. calculated without taking account of the electronhole Coulombic interaction) probability of finding the electron and hole separated by a distance a along the growth (z-) axis. While p(a) is not a physical observable, often the form of it can help in understanding and provide an insight into the nature of the exciton. One particular example of that would be in the 'twin' exciton states of the double quantum well discussed above. Fig. 6.7 shows p(a) for this simple case of the infinite quantum well, while later figures will compare it with other more complex heterostructures.

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In conclusion, the validity of the technique presented above has been substantiated by the calculation of exciton binding energies and wave functions for the full width range of infinite quantum wells. In the sections that follow, examples of calculations will be presented which demonstrate the versatility of the method. In addition, some of the results are expected to be of interest in their own right. 6.6 EXCITONS IN SINGLE QUANTUM WELLS Only in a very few circumstances are the band offsets in both the conduction and valence bands large enough that the system can be approximated with an infinite quantum well model. The vast majority of cases demand finite potentials. Reiterating, the approach developed above depends only upon the one-particle electron and hole wave functions, if}e and -0^, respectively, and no further knowledge of the system is required (except for the basic material parameters of electron and hole effective masses and dielectric constants).

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